A novel poly(vinyl chloride)-supported Pd complex was found to be a highly active catalyst for the Heck and Sonogashira reactions of aryl halides under aerobic conditions. The complex is thermally stable, and can be easily recovered and reused. The catalyst was recycled for the Heck and So-nogashira reactions for five runs without appreciable loss of its catalytic activity, and with negligible metal leaching.
参考文献
| [1] | Chen X;Engle K M;Wang D H;Yu J Q .[J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2009,48:5094. |
| [2] | Mino T;Shirae Y;Sasai Y;Sakamoto M;Fujita T .Phosphine-free palladium catalyzed Mizoroki-Heck reaction using hydrazone as a ligand[J].The Journal of Organic Chemistry,2006(18):6834-6839. |
| [3] | Artuso E;Barbero M;Degani I;Dughera S;Fochi R .Arenediazonium o-benzenedisulfbinimides as efficient reagents for Heck-type arylation reactions[J].Tetrahedron,2006(13):3146-3157. |
| [4] | Fukuyama T;Arai M;Matsubara H;Ryu I .[J].Journal of Organic Chemistry,2004,69:8105. |
| [5] | Bhanage B M;Arai M .[J].Catalysis Reviews-Science and Engineering,2001,43:315. |
| [6] | Sonogashira K. .Development of Pd-Cu catalyzed cross-coupling of terminal acetylenes with sp(2)-carbon halides[J].Journal of Organometallic Chemistry,2002(1/2):46-49. |
| [7] | Negishi E-i;Anastasia L .[J].CHEMICAL REVIEWS,2003,103:1979. |
| [8] | Nicolaou K C;Bulger P G;Sarlah D .[J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2005,44:4442. |
| [9] | Yu CM;Kweon JH;Ho PS;Kang SC;Lee GY .Copper-catalyzed cross- and carbonylative coupling reactions of alkynyliodonium salts with organoboronic acids and organostannanes[J].Synlett,2005(17):2631-2634. |
| [10] | Urgaonkar S;Verkade J G .[J].Journal of Organic Chemistry,2004,69:5752. |
| [11] | Came D E;Du S C;Spenser I D .[J].J Am Chem Soc Perkin Trans 1,2000,122:4213. |
| [12] | Shuttleworth SJ.;Wilson RD.;Nasturica D.;Allin SM. .Functionalised polymers in organic chemistry; Part 2 [Review][J].Synthesis: International Journal of Methods in Synthetic Organic Chemistry,2000(8):1035-1074. |
| [13] | Datta KKR;Eswaramoorthy M;Rao CNR .Water-solubilized aminoclay-metal nanoparticle composites and their novel properties[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2007(7):613-615. |
| [14] | Zhu J;Zhou J H;Zhao T J;Zhou X G Chen D Yuan W K .[J].Applied Catalysis A:General,2009,352:243. |
| [15] | Sidhpuria K B;Patel H A;Parikh P A;Bahadur P Bajaj H C Jasra R V .[J].Applied Clay Seience,2009,42:386. |
| [16] | Li J;Zhang Y M;Han D F;Gao Q Li C .[J].Journal of Molecular Catalysis A:Chemical,2009,298:31. |
| [17] | Choi M;Lee D H;Na K;Yu B W Ryoo R .[J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2009,48:3673. |
| [18] | Pillai U R;Sahle-Demessie E .[J].Green Chemistry,2004,6:161. |
| [19] | Singh V;Ratti R;Kaur S .[J].Journal of Molecular Catalysis A:Chemical,2011,334:13. |
| [20] | Firouzabadi H;Iranpoor N;Kazemi F;Gholinejad M .[J].Journal of Molecular Catalysis A:Chemical,2012,357:154. |
| [21] | Zhang J;?akovi?M;Popovi?Z;Wu H H Liu Y .[J].CATALYSIS COMMUNICATIONS,2012,17:160. |
| [22] | Cui Y C;Zhang L .[J].Journal of Molecular Catalysis A:Chemical,2005,237:120. |
| [23] | Liu J;Li Y Q;Zheng W J .[J].Monatshefte fur Chemie,2009,140:1425. |
| [24] | Bakherad M;Keivanloo A;Amin A H;Jajarmi S .[J].COMPTES RENDUS CHIMIE,2012,15:945. |
| [25] | Bakherad, M.;Keivanloo, A.;Bahramian, B.;Jajarmi, S..Suzuki, Heck, and copper-free Sonogashira reactions catalyzed by 4-amino-5-methyl-3-thio-1,2,4-triazole-functionalized polystyrene resin-supported Pd(II) under aerobic conditions in water[J].Journal of Organometallic Chemistry,2013:206-212. |
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